
Professor Andrew Orr-Ewing
M.A., D.Phil.(Oxon.), CChem FRSC, FRS
Current positions
Professor
School of Chemistry
Contact
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Research interests
The research in my group uses several different types of lasers (including nanosecond and femtosecond pulsed lasers, and cw lasers) to study chemical reactivity, atmospheric chemistry, methods of trace gas detection, optical properties of aerosol particles, and molecular spectroscopy and photochemistry. We use ultrafast transient absorption spectroscopy to study chemical and photochemical reaction dynamics in liquids, and cavity enhanced spectroscopy methods for a variety of applications in atmospheric chemistry and aerosol science. In addition, we use computational methods such as ab initio electronic structure theory and molecular dynamics to aid the interpretation of experimental measurements. I was the lead investigator on the ERC Advanced Grant CAPRI (Chemical and Photochemical Dynamics of Reactions in Solution, 2012-2017) and my group is part of the EPSRC-funded Programme Grant Ultrafast Photochemical Dynamics in Complex Environments. We also collaborate with Bristol colleagues Prof Jonathan Reid, Prof Dudley Shallcross, Prof Varinder Aggarwal, Dr Tom Oliver, Dr Beatrice Collins, Dr Michael Cotterell and Dr Bryan Bzdek on various of the above research projects.
Further details of my group's research activities can be found at the homepage of the Laser Chemistry, Spectroscopy and Dynamics Group and a full list of my publications is available here.
Our studies of reaction dynamics on ultrafast timescales in liquid solutions were published in Science in 2011. The cover picture shows reaction of CN radicals with cyclohexane in solution in dichloromethane. Theoretical insights from this work were published in 2011 in Nature Chemistry and also featured on the cover. A paper on F-atom reactions in solution appeared in Science in 2015.
Professor Orr-Ewing is a supervisor in the EPSRC Centre for Doctoral Training in Chemical Synthesis and the EPSRC Centre for Doctoral Training in Aerosol and Droplet Science.
Projects and supervisions
Research projects
Saurabh Khodia: Formation of organic particles in the atmosphere by stabilized Criegee intermediate chemistry
Principal Investigator
Managing organisational unit
School of ChemistryDates
15/01/2024 to 14/01/2027
Transfer back from Oxford - New Approaches For Measuring Accelerated Chemical Reactions In Single Aerosol Particles
Principal Investigator
Managing organisational unit
School of ChemistryDates
04/09/2023 to 31/12/2024
Michael Price URF Enhanced Research Expenses
Principal Investigator
Managing organisational unit
School of ChemistryDates
01/05/2023 to 30/04/2028
Stefan Vuckovic - Enhanced Research Expenses - Royal Society
Principal Investigator
Managing organisational unit
School of ChemistryDates
01/01/2023 to 31/03/2023
Emitters
Principal Investigator
Managing organisational unit
School of ChemistryDates
01/10/2022 to 30/09/2027
Thesis supervisions
Exploring the Role of Solvents on the Chemical Dynamics of Reactive Intermediates using Ultrafast Transient Absorption Spectroscopy
Supervisors
Experimental and Computational Investigation of Molecular Photodissociation and Scattering Dynamics
Supervisors
Ultrafast photoinduced bimolecular proton, electron and energy transfer
Supervisors
The Photochemistry of Conjugated Enolates
Supervisors
Ab initio methods for atmospheric photochemistry
Supervisors
Transient absorption spectroscopy studies of photochemical reactions initiated by electron transfer
Supervisors
Photochemical reaction dynamics of organic chromophores in solution investigated with ultrafast transient absorption spectroscopy
Supervisors
Investigating Functional Organic Molecules in Solution Using Ultrafast Spectroscopy
Supervisors
Gold cross-coupling reactions
Supervisors
Development of conjugated microporous polymers for energy storage applications
Supervisors
Publications
Recent publications
12/09/2024Competing non-adiabatic relaxation pathways for near-UV excited ortho-nitrophenol in aqueous solution
Journal of Physical Chemistry Letters
Efficient Ground-State Recovery of UV-Photoexcited p-Nitrophenol in Aqueous Solution by Direct and Multistep Pathways.
Journal of the American Chemical Society
Exchange, promiscuity, and orthogonality in de novo designed coiled-coil peptide assemblies
Chemical Science